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Why Yes, Serena and Nate may have first gotten together behind her best friend's back.Their hookup was the moment that started everything, really.That provided a reason to root for them to be together and break up. It was obvious Nate and Blair never would (or should) have stayed together from the beginning.Their relationship seemed to exist to be the source of conflict in season 1 for Blair and Serena's friendship. It was clear from the very start that Serena and Dan would end up together.
With others in the series based on the books by Cecily von Ziegesar, it was not.
With at least one pairing, it was a relief that the series took that step from friends to more for a little while.
In at least one case, having two characters get (and stay) together was the right move.
Considering the series followed a group of friends from high school to post-college careers, romance was inevitable.
For a series on the CW, relationship drama is also a sure thing for most, if not all, couples.
In the first two seasons, they got together, broke up and then got back together.